For manufacturers in Southeast Asia looking to sell on Alibaba.com, understanding intergranular corrosion is critical when supplying stainless steel components for welded structures. This form of corrosion occurs along the grain boundaries of stainless steel, often invisible to the naked eye until catastrophic failure occurs. The phenomenon is particularly relevant for industries including chemical processing, food equipment manufacturing, marine applications, and architectural welding projects where structural integrity cannot be compromised.
What Exactly Is Intergranular Corrosion? Intergranular corrosion is a localized attack that progresses along the grain boundaries of metal, leaving the bulk of the grains largely unaffected. In stainless steel, this occurs when chromium carbides precipitate at grain boundaries during exposure to specific temperature ranges, depleting the adjacent areas of chromium—the very element that provides stainless steel's corrosion resistance. When chromium content drops below approximately 12% in these boundary regions, the material becomes susceptible to corrosive attack [2].
The Sensitization Mechanism Explained: During welding, the heat-affected zone (HAZ) experiences temperatures within the sensitization range. At these temperatures, carbon atoms in the steel migrate to grain boundaries and combine with chromium to form chromium carbides (Cr23C6). This process, called sensitization, creates chromium-depleted zones adjacent to the grain boundaries. These depleted zones become anodic relative to the chromium-rich grains, setting up a galvanic cell that accelerates corrosion along the boundaries [3].
Sensitization is the precipitation of chromium carbides at grain boundaries when stainless steel is heated in the range of 425-815°C. This causes chromium depletion in the adjacent areas, making them susceptible to intergranular corrosion. The best prevention methods include using low-carbon L-grades, solution annealing, or stabilized grades with titanium or niobium additions [2].

