Micro-arc oxidation (MAO), also known as plasma electrolytic oxidation (PEO), is an electrochemical surface treatment that converts metal surfaces—primarily aluminum, magnesium, and titanium alloys—into dense, ceramic-like oxide layers. Unlike traditional anodizing, MAO operates at higher voltages, creating micro-discharges that form a crystalline ceramic coating integrated with the substrate [4].
The MAO process creates a coating that is fundamentally different from applied paints or sprays. It's a conversion coating, meaning the outer layer of the metal itself is transformed into a ceramic oxide. This results in exceptional adhesion, as the coating is not a separate layer but an extension of the base material. For B2B buyers sourcing on Alibaba.com, understanding this distinction is critical when evaluating supplier capabilities and coating specifications.
The coating structure typically consists of two layers: a dense inner barrier layer and a porous outer layer. Recent research demonstrates that additive modifications—such as tungsten oxide (WO3) or graphene oxide dispersion—can further enhance coating compactness, reducing porosity from 15% to 9.37% and increasing thickness from 3.06μm to 5.72μm [5].

